Observer wrote:zompist, I can work them out that way, however, I can't necessarily see how such a concept would work as a non-derived root. P & Q is easy. "Cake and ice cream." How would "P but not Q" work as a word like "and?" Let's invent the word "zog" to mean "P but not Q." "You can have cake zog ice cream." I can't imagine someone actually saying that. One would simply say, "Do you want cake?" Why offer a choice that's not available? When would a morphemic word for such constructions as "P but not Q" ever be used in everyday speech? Perhaps the reason all fourteen logical connectors don't appear as non-derived roots in any language is because they aren't useful in colloquial speech. I can't see their potential use. Can you?
You can't imagine anyone actually saying "but not"?
That phrase is used all the time. Part of your trouble imagining it being used may be that you seem to be restricting your examples to situations in which someone is offering someone else a choice. (That said, I don't even think "you can have cake but not ice cream" sounds strange at all). Googling the phrase gave me hits like "in the world but not of the world," "down but not out," "why Kosovo but not Palestine," "abandoned but not forgotten," and many more. The common thread being that the conjoints would normally seem to belong together (the second being an implication of the first), but against expectations, do not.
I would not be at all surprised if one or more natlang out there has a non-derived word for "but not." I can also imagine a contraction of "but not" arising, and eventually replacing the two words.